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Bite-sized lesson

GCSE Chemistry — Pure Substances, Potable Water & Treatment

GCSE Chemistry · Ages 14–16

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Taught through the animal room water supply

Approx. 55 minutes · KS4 · Also usable as two halves

Before you start

Every animal at Pets on the Green drinks, swims in, or is misted with water that came out of a tap in Surrey. Almost none of them can have it straight.

This lesson is about why, and it covers a large slice of the GCSE Chemistry specification on purity, potable water and separation techniques.

There is no timer. Stop wherever you like.

What you'll be able to do by the end

Part 1 — Two meanings of "pure"

A bottle of spring water says pure on the label. In chemistry, that label is wrong.

In chemistry, a pure substance is a single element or a single compound, with nothing else in it.

Spring water is water plus dissolved calcium, magnesium, sodium, chloride, sulfate and more. It is a mixture. The label means "nothing nasty added," which is an everyday meaning, not a chemical one.

How you can tell, without a lab

A pure substance melts and boils at fixed, specific temperatures. Pure water boils at exactly 100 °C at atmospheric pressure and freezes at exactly 0 °C.

A mixture melts and boils across a range, and the presence of dissolved solute shifts those points — boiling point up, freezing point down.

Exam useIf you are given melting or boiling data and asked whether a sample is pure, look for a sharp point versus a range. That is almost always what the question is testing.

Check yourself

The terrapin pool is topped up with tap water. A sample is heated and begins to boil at 100.4 °C, with the temperature continuing to rise slowly as it boils.

Is this sample pure water? Justify your answer.

Answer

No. Pure water boils at a fixed 100 °C. This sample boils above 100 °C and over a range rather than at a single temperature, which indicates dissolved solutes — so it is a mixture.

Part 2 — Potable water is not pure water

Potable water is water that is safe to drink. That is a different test from chemical purity.

Potable water is allowed to contain dissolved substances. It must simply have low enough levels of dissolved salts and no harmful microbes. Tap water is a mixture, and deliberately so.

How UK tap water is made potable

  1. Choose the source. Fresh water from reservoirs, rivers or aquifers — low in dissolved salts to begin with.
  2. Sedimentation. Large solids settle out.
  3. Filtration. Passed through filter beds of sand and gravel to remove finer insoluble solids.
  4. Sterilisation. Microbes killed — by chlorine, ozone, or ultraviolet light.

Note what step 4 does. It puts something in.

Part 3 — Where this becomes an animal welfare problem

Chlorine is added to tap water precisely because it is toxic to microorganisms. That property does not switch off when the water reaches an aquarium.

Fish and aquatic amphibians. Chlorine damages gill tissue. In an enclosed tank there is no dilution and nowhere to escape to. Water for the tropical tank and the terrapins is dechlorinated before it goes anywhere near an animal.

Amphibians in general. White's tree frogs and the African bullfrog absorb water and dissolved substances directly through permeable skin. They do not have the barrier a mammal has. What is in the water goes into the animal.

Two ways to remove it. Chlorine is a dissolved gas and will leave standing water over about 24 hours. A chemical dechlorinator — usually sodium thiosulfate — does it in minutes by reducing the chlorine to chloride ions. Where a supplier uses chloramine rather than chlorine, standing will not work, because chloramine is far more stable and does not readily leave solution.

The mistake that kills fish"I left it in a bucket overnight" is sound reasoning for chlorine and useless for chloramine. Which one is in your supply depends on your water company. This is a case where the chemistry determines the husbandry, and getting the chemistry wrong kills the animal.

Check yourself

A keeper adds sodium thiosulfate to a bucket of tap water before filling a frog enclosure.

Explain what the sodium thiosulfate does, and why the frog is at greater risk from untreated water than a mammal would be.

Answer

Sodium thiosulfate reduces chlorine to chloride ions, which are harmless at these concentrations. The frog is at greater risk because amphibian skin is permeable and used for water and gas exchange, so dissolved substances pass directly into the body rather than being blocked by a keratinised barrier.

Part 4 — Hard water and limescale

Surrey sits on chalk. Rainwater, which is slightly acidic from dissolved carbon dioxide, passes through it and dissolves calcium and magnesium compounds. The result is hard water — water containing dissolved calcium and magnesium ions.

When hard water is heated or evaporates, those ions come out of solution as solid calcium carbonate: limescale.

In an animal room this shows up constantly:

That last one is a demonstration of a chemical idea you will be examined on. When a solution evaporates, the solvent leaves and the solute remains. The mark on the glass is the dissolved solids, made visible.

Check yourself

Explain, in terms of dissolved ions, why a misting system in Surrey blocks more often than the same system in a soft-water area.

Answer

Surrey water is hard, meaning it contains a high concentration of dissolved calcium and magnesium ions from chalk. As water evaporates at the nozzle, these ions are left behind and form solid calcium carbonate. In a soft-water area the concentration of these ions is much lower, so far less solid is deposited.

Part 5 — Getting to actually pure water

Sometimes potable is not enough. Reptile misting systems and some aquarium setups need water with the dissolved solids removed, or the scale problem never stops.

Distillation. Boil the water, condense the vapour, collect the distillate. The dissolved solids have much higher boiling points and stay behind. Produces very pure water. Enormously energy-expensive, which is why it is used at small scale and not for a public supply.

Reverse osmosis. Force water through a partially permeable membrane under pressure. The membrane passes water molecules and holds back dissolved ions. Cheaper to run than distillation, and it is the method used to desalinate seawater.

Why not use these for tap water? Cost and energy. Treating an entire city's supply this way would be indefensible when filtration and sterilisation produce water that is already safe to drink.

Choosing the right method

ProblemMethodWhy
Sand and debris in pond waterFiltrationRemoves insoluble solids only
Need to know how much is dissolved in a sampleEvaporationSolvent leaves, solute remains and can be weighed
Need water with dissolved ions removedDistillation or reverse osmosisSeparates dissolved solutes from the solvent
Water may carry microbesSterilisationFiltration does not kill microorganisms
The distinction that carries marksFiltration removes what is insoluble. It does nothing to anything dissolved. A very large number of lost marks come from answers that filter a solution and expect the salt to be gone.

Part 6 — Exam-style questions

1. A student says bottled spring water is pure. Explain why a chemist would disagree. (2 marks)

Mark scheme

1 mark: in chemistry a pure substance is a single element or compound.

1 mark: spring water contains dissolved minerals or ions, so it is a mixture.

2. Describe the stages used to treat fresh water to make it potable, and state the purpose of each. (4 marks)

Mark scheme

1 mark each, to a maximum of 4: choosing an appropriate source low in dissolved salts; sedimentation to settle large solids; filtration through sand and gravel to remove finer insoluble solids; sterilisation using chlorine, ozone or UV to kill microorganisms.

3. Tap water is safe for humans but must be treated before use in a tropical fish tank. Explain why. (3 marks)

Mark scheme

1 mark: tap water contains chlorine, added during sterilisation.

1 mark: chlorine is toxic to fish / damages gill tissue.

1 mark: it can be removed by standing the water or by adding a dechlorinator such as sodium thiosulfate.

Credit also available for identifying that chloramine, where used, will not leave solution by standing.

4. A sample of water from an animal enclosure is suspected to contain dissolved solids. Describe a practical method to determine whether it does, and how you would use the result. (4 marks)

Mark scheme

1 mark: measure a known volume or mass of the sample.

1 mark: evaporate to dryness in a weighed evaporating basin, gently.

1 mark: reweigh; any increase in mass is the dissolved solid remaining.

1 mark: dissolved solid concentration calculated from mass of residue against volume of sample.

Credit for a stated comparison against a distilled water control.

5. Explain why distillation is used to purify water in a laboratory but not to supply water to a city. (3 marks)

Mark scheme

1 mark: distillation produces very pure water by boiling and condensing, leaving dissolved solids behind.

1 mark: it requires very large amounts of energy to boil the water.

1 mark: this makes it too expensive at the scale of a public supply, where filtration and sterilisation already produce potable water.

If you want to go further

Notes for the adult

Curriculum: GCSE Chemistry — pure substances, formulations, potable water, and separation techniques including filtration, evaporation, distillation and reverse osmosis. Overlaps with the required practical on the analysis and purification of water samples.

The misconception this lesson targets: that "pure" and "safe" mean the same thing, and that filtration removes dissolved substances. Both are addressed directly rather than left to correct themselves.

Running it in halves: Parts 1–3 stand alone as a session on purity and potable water. Parts 4–6 cover hardness and separation and assume the first half has been done.

A note on the chloramine point. It is beyond the specification and is included because it is true and because it is the kind of detail that makes a student trust the material. It is flagged as extension credit in question 3 rather than required.

Access: read-aloud, dyslexia-friendly font, enlarged text, high contrast and calm mode on every page, changeable mid-lesson. Answer sections collapse by default and can be set to stay open.

No timing, no scoring. Nothing here is marked, logged or reported.

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